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Synthesis, Crystal Structure and Properties of a New Phosphate, Na2Co2Cr(PO4)(3)

Abstract : In this work, a novel phosphate Na2Co2Cr(PO4)(3) was synthesized by sol-gel method, and its crystal structure was determined from powder X-ray diffraction data using Rietveld method. This new phosphate was further characterized by scanning electron microscopy, IR and Raman spectroscopy. This phosphate crystallizes in the well-known alluaudite-type structure with monoclinc symmetry (S.G. C 2/c). The structure of this phosphate consists of [CoO6] octahedra, [(Co,Cr)(2)O-10] dimer-octahedra and PO4 tetrahedra leading to an open three-dimensional framework containing two types of tunnels running along [001] direction, where Na+ cations are located. The magnetic measurements confirmed that the predominant interactions in this phosphate are antiferromagnetic with a Curie-Weiss constant of =-4.57K. The electrochemical properties of Na2Co2Cr(PO4)(3) as anode material for sodium-ion batteries were assessed using a galvanostatic mode and cyclic voltammetry in the potential window of 0.02-3V. The electrochemical behavior was investigated by ex situ X-ray diffraction. The results showed that this material undergoes a conversion-type reaction.
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https://hal-u-picardie.archives-ouvertes.fr/hal-03627231
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Soumis le : vendredi 1 avril 2022 - 10:45:17
Dernière modification le : dimanche 3 avril 2022 - 03:28:21

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Mohammed Hadouchi, Abderrazzak Assani, Mohamed Saadi, Ismael Saadoune, Abdelilah Lahmar, et al.. Synthesis, Crystal Structure and Properties of a New Phosphate, Na2Co2Cr(PO4)(3). JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS, 2018, 28 (6), pp.2854-2864. ⟨10.1007/s10904-018-0956-y⟩. ⟨hal-03627231⟩

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