Unexpectedly high Curie temperature in weakly strained ferroelectric film
Résumé
Polarized Raman spectra of the epitaxial Ba0.4Sr0.6TiO3 film grown on MgO substrate with thickness of 600nm were studied in a broad temperature range of 80-600K and the phase transition from paraelectric to tetragonal ferroelectric phase was observed at about 500K. This critical temperature is substantially higher than that calculated from the lattice-mismatch strain theory. In addition, the predicted from the theory low-temperature orthorhombic and rhombohedral phases were not observed. We ascribe the strengthening of the tetragonal ferroelectric phase to the effect of the interface-induced build-in electric field resulted from the interface-accumulated charges.