Recent Advances in the Synthesis of Five-Membered Cyclic Carbonates and Carbamates from Allylic or Propargylic Substrates and CO2 - Université de Picardie Jules Verne Accéder directement au contenu
Article Dans Une Revue Catalysts Année : 2022

Recent Advances in the Synthesis of Five-Membered Cyclic Carbonates and Carbamates from Allylic or Propargylic Substrates and CO2

Filip Vranjesevic
  • Fonction : Auteur
Maria Kolympadi Markovic
  • Fonction : Auteur
Dario Matulja
  • Fonction : Auteur
Gabriela Ambrozic
  • Fonction : Auteur
Jose Angel Sordo
  • Fonction : Auteur
Valerije Vrcek
  • Fonction : Auteur
Dean Markovic
  • Fonction : Auteur

Résumé

The organic carbamates and carbonates are highly desirable compounds that have found a wide range of applications in drug design, medicinal chemistry, material science, and the polymer industry. The development of new catalytic carbonate and carbamate forming reactions, which employ carbon dioxide as a cheap, green, abundant, and easily available reagent, would thus represent an ideal substitution for existing methods. In this review, the advancements in the catalytic conversion of allylic and propargylic alcohols and amines to corresponding five-membered cyclic carbonates and carbamates are summarized. Both the metal- and the organocatalyzed methods are reviewed, as well as the proposed mechanisms and key intermediates of the illustrated carbonate and carbamate forming reactions.

Domaines

Catalyse

Dates et versions

hal-03696972 , version 1 (16-06-2022)

Identifiants

Citer

Filip Vranjesevic, Maria Kolympadi Markovic, Dario Matulja, Gabriela Ambrozic, Jose Angel Sordo, et al.. Recent Advances in the Synthesis of Five-Membered Cyclic Carbonates and Carbamates from Allylic or Propargylic Substrates and CO2. Catalysts, 2022, 12 (5), ⟨10.3390/catal12050547⟩. ⟨hal-03696972⟩
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