Accéder directement au contenu Accéder directement à la navigation
Article dans une revue

Structural, dielectric and electrocaloric properties of (Ba0.85Ca0.15)(Ti0.9Zr0.1-xSnx)O-3 ceramics elaborated by sol-gel method

Abstract : Ferroelectric ceramics (Ba0.85Ca0.15)(Ti0.9Zr0.1-xSnx)O-3 (x = 0.00, 0.02, 0.04, 0.06) were elaborated by sol-gel method. Structural investigation revealed co-existence of tetragonal (P4mm) and orthorhombic (Pmm2) symmetries at room temperature for the undoped ceramic, while only a tetragonal structure (P4mm) was observed for the doped ceramics. Dielectric measurements indicate a dielectric relaxation process at high temperatures which is essentially related to the hopping of oxygen vacancies. Furthermore, a down shifting of the Curie temperature (T-C) with increasing Sn4+ doping rate has been revealed. The temperature profiles of the Raman spectra unveiled the existence of polar nanoregions above the Curie temperature in all ceramics. The ferroelectric properties were found to be related to the microstructure. Electrocaloric effect was investigated in this system that revealed an electrocaloric responsivity of 0.225 x 10(-6) K m/V for the composition with x = 0.04 Sn doping, where other remarkable physical properties were also observed.
Type de document :
Article dans une revue
Liste complète des métadonnées
Contributeur : Louise DESSAIVRE Connectez-vous pour contacter le contributeur
Soumis le : vendredi 1 avril 2022 - 13:47:16
Dernière modification le : lundi 12 septembre 2022 - 10:14:27

Lien texte intégral




S. Belkhadir, A. Neqali, M. Amjoud, D. Mezzane, A. Alimoussa, et al.. Structural, dielectric and electrocaloric properties of (Ba0.85Ca0.15)(Ti0.9Zr0.1-xSnx)O-3 ceramics elaborated by sol-gel method. Journal of Materials Science: Materials in Electronics, Springer Verlag, 2019, 30 (15), pp.14099-14111. ⟨10.1007/s10854-019-01776-1⟩. ⟨hal-03627565⟩



Consultations de la notice